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  • Modeling of changes of physicochemical characteristics of potash fertilizers at storage and transportation

    A model system was designed and test  trials of physical and mechanical characteristics of small – crystalline and granular flotation potassium chloride are studied. This model system allows to design storage and transportation  of fertilizers in bulk in railway wagons and it has the same static and vibrational load as real system. The effect of temperature and relative humidity of the air on hygroscopy of small – crystalline and granular КСl were studied. Furthermore the influence of static load, and time length  of compression process of fertilizing layer and parameters of static and vibrational load on composition of КСl granules were investigated. It was experimentally proved that the humidity increase (0,5 %) of granular КСl and the  increase of static load and time length  of compression process of product during transportation in bulk lead to increase of compaction degree and caking ability of product. Research of the influence of high static load (10-30 kg/sm2) and time length of compression process of fertilizing layer on caking ability and degree of compaction show that small – grained KCl has smaller degree of compaction and considerably higher value of caking ability in comparison with granular KCl.

    Keywords: Potash fertilizers, storage and transportation, hygroscopy, caking ability, degree of compaction, commodity characteristics of fertilizers

  • Kinetics of sylvinite ore desliming under ultrasonic treatment

    Operation of sylvinite ore desliming is an important step of potassium chloride production by floatation method. It is known that ultrasonic treatment is applied to increase the efficiency of insoluble rest separating from an ore. The purpose was to establish kinetic regularities of the insoluble rest removal from sylvinite ore crystals of the same particle size distribution. Investigations were carried out with mechanical stirring and sonication of varying intensity. It is established that process of sylvinite ore desliming occurs in the diffusion mode. Application of ultrasonic treatment allows to intensify process in 2-4 times as compared with mechanical desliming. Influence of sylvinite ore treatment parameters to chemical composition changing of the insoluble rest is defined. It is shown that sonication for 90 seconds leads to removing carbonates from ore crystals withal concentrating of the iron compounds.

    Keywords: desliming, sylvinite ore, ultrasonic treatment, sonication, insoluble rest.

  • Research of process of wettability of pulverulent potassium chloride containing the admixtures of flotoreagents

    The express-method of estimate of the rate of wetting  of pulverulent powder of KCl is developed. The wettability of potassium chloride powder containing the admixtures of flotoreagents by solutions of different binders is studied.

    Keywords: wettability, flotoreagent, binder, transformation, muriatic amine, sodium metasilicate