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  • Formation of array nanoparticles during electrodeposition platinum on glassy carbon and dispersed carbon support

    In the present study, platinum was electrodeposited onto rotating disc electrode coated with Vulcan XC-72R Nafion suspension and uncoated smooth glassy carbon electrode from acidic solution of 5mМ H2PtCl6. The electrochemically active surface area of platinum particles obtained was determined by cyclic voltammetry and the structural characteristic of the particles was studied by scanning electron microscopy. The impact of current and time on the electrochemically active surface area of platinum particles electrodeposited on the carbon supports was also investigated and described in this paper. The present work is expected to be utilized and contribute to the improvement of electrochemically active surface area of platinum catalysts for low temperature fuel cells.

    Keywords: galvanostatic electrodeposition, chronopotentiometric curves, chloroplatinic acid, vulcan XC-72R, fuel cells

  • Determination of the atomic structure of bimetallic Pt-Ag nanoparticles in metal-carbon catalysts by X-ray absorption spectroscopy data

    The atomic structure of bimetallic nanoparticles of Pt-Ag composition, which are the part of metal-carbon electro-catalysts PtAg/C, is studied by means of EXAFS spectroscopy using the suggested technique. These materials have been prepared by methods of consistent and simultaneous deposition of Ag and Pt atoms from aqueous ethylene glycol solutions of their salts with subsequent acid treatment. The values ​​of the structural parameters of the near environment of platinum atoms are determined. The nature of the distribution of components in nanoparticles is established. Cluster models of nanoparticles are constructed. The fraction of Pt atoms in the working shell and its dependance on preparation methods in each case are determined.

    Keywords: Metal-carbon electrocatalysts, bimetallic nanoparticles, Catalysis, Platinum, X-ray absorption spectroscopy, atomic structure

  • Comparative study of the catalytic activity Pt/C and PtхNi/C materials in the oxygen electroreduction

    The catalytic activity of Pt/C and PtxNi/C electrocatalysts prepared by  borohydride methode was studed. It was established that the specific activity  of fresh prepared Pt3,7Ni/C  catalyst  in oxygen  electroreduction  reaction is higher in compare with Pt/C material. After treatment of Pt3,7Ni/C material in the hot acid  nickel in the surface layers of nanoparticles was dissolved and the composition of nanoparticles was changed to Pt5,6Ni. The electrochemical surface area of the Pt5,6Ni catalyst and specific activity was slightly decreased after corrosion treatment. 

    Keywords: platinum electrocatalysts, corrosion stability of the nanoparticles, fuel cells, X-ray diffraction, borohydride synthesis